Technetium and the actinides are radioelements of importance to the nuclear fuel cycle.  Compounds composed of these elements are used in nuclear fuel, separations, safeguard applications, and isotope utilization.  These radioelements also represent an underexplored section of the periodic table.  Studies on compounds with technetium and the actinides provide opportunities to expand basic chemical knowledge, particularly when coupled with computational studies.  Performing experiments with these elements requires specialized facilities and radiochemical expertise.  The radiochemistry program at the University of Nevada, Las Vegas is described, with emphasis given to the facilities, education mission, and collaborations.