简介: |
CV and Publications
Professional
2011-present Professor, University of British Columbia
2007-2011 Associate Professor, University of British Columbia
2001-2007 Assistant Professor, University of British Columbia
Education
1999-2001 NSERC Post-Doctoral Fellow (Organic Chemistry, MIT)
Advisor: Timothy M. Swager
1995-1999 Ph.D. (Inorganic Chemistry, University of Toronto)
Advisors: Ian Manners and Geoffrey A. Ozin
Thesis: “New Directions in Inorganic Polymer and Materials Chemistry: Studies of Metal Germanium
Sulfides, Ferrocene-Containing Materials, and Mesoporous Silica - Poly(Ferrocenylsilane) Composites”
1991-1995 B. Sc. (Honours Chemistry, University of British Columbia)
Additional Research Experience
09/2009-05/2010 Alexander von Humboldt Fellow with Markus Albrecht (RWTH Aachen, Germany)
05/1995-07/1995 Research Student at the Department of Chemistry, Memorial University of Newfoundland
Advisor: Prof. Laurence K. Thompson (NSERC USRA Program)
05/1994-08/1994 Research Student at the Department of Chemistry, McGill University
Advisor: Prof. Mark P. Andrews (NSERC USRA Program)
Professional Activities and Affiliations
1995-present Member, Chemical Society of Canada (Inorganic and Materials Divisions) & ACS
2010-present Treasurer, Materials Division of the CSC
2012 Co-organizer of BC Inorganic Discussion Weekend
2012 Co-Organizer of Canada-Japan Joint Symposium for Supramolecular Nanomaterials Chemistry
2010 Co-Organizer of Pacifichem Symposium (in Inorganic Chemistry)
2009 Co-organizer of CSC Conference Symposium (in Inorganic Chemistry)
2007-2010 Nanoscience and Materials Area Coordinator for Pacifichem 2010
2007-2008 Chair, NSERC Chemistry Scholarships and Fellowships Selection Committee (#179)
2005-2007 Member, NSERC Chemistry Scholarships and Fellowships Selection Committee (#179)
2002-2008 Nine appearances on “Shopping Bags” (Women’s Television Network)
Awards
2012-2014 E.W.R. Steacie Memorial Fellowship NSERC
2011 Killam Research Prize UBC
2009-10 Alexander von Humboldt Fellowship RWTH Aachen, Germany
2008 Killam Prize for Excellence in Teaching UBC
2007 CNC-IUPAC Travel Award CNC-IUPAC
2005 Killam Teaching Achievement Award UBC
2000 NSERC Doctoral Prize NSERC
1999-2001 NSERC Post-Doctoral Fellowship NSERC
1998 Inorganic Seminar Creativity Award University of Toronto
1997-1999 NSERC Post-Graduate Scholarship (PGSB) NSERC
1998, 1997 Beamish Prize in Inorganic Chemistry University of Toronto
1997 Beamish Prize in Inorganic Chemistry University of Toronto
1995-1997 Post-Graduate Scholarship (PGSA) NSERC
1995 NSERC USRA Memorial University
1994 NSERC USRA McGill University
Invited Lectures (Chemistry departments unless otherwise noted)
06/2013 Gordon Research Conference on Liquid Crystals (Invited Speaker), upcoming 06/2013.
12/2012 RSC Supramolecular and Macrocycle Chemistry Meeting (Dec. 17/18, 2012), upcoming.
11/2012 Young Scientists Workshop on Soft Interface Sciences, Advanced Industrial Science and Technology, Tskuba, Japan. November 2012. Upcoming.
11/2012 Keith Fagnou Memorial Lectureship, University of Ottawa, upcoming 7/11/2012.
10/2012 Memorial University of Newfoundland, upcoming 10/2012
09/2012 Invited Lecture Tour in Beijing (ICCAS, Peking University, and Tsinghua University), upcoming 09/2012
08/2012 ACS Fall Meeting, Philadelphia, PA
06/2012 ACS Northwest Regional Meeting (NORM12), Boise, ID.
05/2012 Canada-Japan Symposium for Supramolecular Nanomaterials Chemistry, Whistler, BC
05/2012 Inorganic Discussion Weekend, Squamish, BC, Plenary Speaker
05/2012 10th Centre for Self-Assembled Chemical Structures (CSACS) Symposium, Montreal
05/2012 Western Canada Undergraduate Chemistry Conference, Edmonton, AB, Plenary Speaker
04/2012 Texas A&M University, College Station
04/2012 University of Texas, Austin
03/2012 ACS Conference (San Diego)
03/2012 Bowling Green State University, Ohio
03/2012 Celebrate Research, UBC
01/2012 Int’l Symp. on Macrocyclic and Supramolecular Chemistry (ISMSC), New Zealand, Keynote Lecture
11/2011 Kyushu University Global COE “Science for Future Molecular Systems” Symposium
08/2011 13th International Conference on Ferroelectric Liquid Crystals (Niagara, ON)
07/2011 SeLeCa Symposium, RWTH, Aachen, Germany
06/2011 CSC Conference, Montreal, PQ (Metallosupramolecular Assemblies Symposium)
04/2011 Hong Kong University
04/2011 Hong Kong University of Science and Technology
04/2011 City University of Hong Kong, Distinguished Lecture Series
04/2011 Xerox Research Centre of Canada Lecture Series
03/2011 Café Scientifique, Railway Club, Vancouver
01/2011 U. Laval, Quebec
12/2010 Pacifichem 2010, Honolulu, HI (Designed Pi Systems - Synthesis, Properties, Theory & Function Symp.)
12/2010 Pacifichem 2010, Honolulu, HI (Structural and Functional Aspects of Coordination Polymers Symp.)
12/2010 Pacifichem 2010, Honolulu, HI (Self-Assembly and Coordination Chemistry Symposium)
12/2010 Materials Science Institute Retreat (Oregon; Student Invited Speaker)
11/2010 University of British Columbia, Lectures in Modern Chemistry
10/2010 Idaho State University
06/2010 Progress in Paper Physics Seminars (PPPS) 2010, Montreal, PQ (Keynote Lecture)
06/2010 CSC Conference, Toronto, ON (Ring, Chains, & Polymers With Inorganic Elements Symp.)
05/2010 Universität Leipzig, Germany
04/2010 Università della Basilicata, Potenza, Italy
04/2010 Universität Bielefeld, Germany (GDCh Invited Lectureship)
04/2010 Universität Braunschweig, Germany
04/2010 Universität Hamburg, Germany
03/2010 Institut Català d’Investigació Química (ICIQ), Tarragona, Spain,
02/2010 Universität Siegen, Germany
01/2010 Universität Ulm, Germany (GDCh Invited Lectureship)
01/2010 Freie Universität Berlin, Germany
01/2010 Universität Dresden, Germany
12/2009 Universität Essen-Duisburg, Germany
11/2009 Universität Münster, Germany
11/2009 Universität Bonn, Germany
11/2009 Universität Würtzburg, Germany
11/2009 FPInnovations Nanotechnology Partners’ Meeting, Montreal, PQ
10/2009 RWTH Aachen, Germany
08/2009 Paprican Research Centre, Vancouver, BC
08/2009 ACS Conference Fall 2009, Washington, DC
07/2009 Japan-Canada Coordination Space Symposium, Banff, AB
05/2009 Western Canada Undergraduate Chemistry Conference, Tri-Rivers University, Kamloops, BC
03/2009 Université de Sherbrooke, Sherbrooke, PQ (Centre for Self-Assembled Chemical Structures Lecture)
03/2009 Université de Montréal, Montreal, PQ (Centre for Self-Assembled Chemical Structures Lecture)
03/2009 McGill University, Montreal, PQ (Centre for Self-Assembled Chemical Structures Lecture)
03/2009 University of Calgary, Calgary, AB
09/2008 Memorial University of Newfoundland, St. John’s, NF
06/2008 FPInnovations Nanotechnology Partners Meeting, Pointe-Claire, PQ
03/2008 University of Saskatchewan, Saskatoon, SK
08/2007 ACS Conference Fall 2007, Boston, MA (given by J. Hui in my absence)
08/2007 12th IUPAC International Symposium on Macromolecular Complexes, Fukuoka, Japan
07/2007 Inorganic Chemistry Gordon Research Conference, Salve Regina University (RI)
04/2007 University of Victoria, Victoria, BC
01/2007 ASM Vancouver Chapter Meeting, Richmond, BC
01/2007 UBC Okanagan, Kelowna, BC
12/2006 University of Windsor, Windsor, ON
09/2006 ACS Conference Fall 2006, San Francisco, CA (Electroactive and Photoresponsive Metal-Containing Polymers Symposium)
09/2006 ACS Conference Fall 2006, San Francisco, CA (Molecular Containers Symposium)
12/2005 Pacifichem 2005, Honolulu, HI (Inorganic-Organic Hybrid Main Chain Polymers Symposium)
12/2005 Pacifichem 2005, Honolulu, HI (Self-Assembled Materials and Liquid Crystals Symposium)
08/2005 11th International Symposium for Novel Aromatic Compounds (ISNA), St. John’s, NF
05/2005 CSC Conference 2005, Saskatoon, SK
03/2005 ACS Conference Spring 2005, San Diego, CA
03/2005 University of Washington, Seattle, WA
02/2005 Frontiers in Molecular Magnetism, Pacific Institute for Theoretical Physics, Vancouver, BC
01/2005 Symposium on Polymer and Molecular Electronics and Devices, Singapore
11/2004 Canadian Space Agency Physical Sciences Review, Montreal, PQ
05/2004 Xerox Distinguished Lecture Series, XRCC, Mississauga, ON
06/2004 87th CSC Conference, London, ON
03/2004 ACS Conference Spring 2004, Anaheim, CA
12/2003 Pacific Centre for Advanced Materials and Microstructures Conference, Vancouver
08/2003 39th IUPAC Congress and 86th CSC Conference, Ottawa, ON
PUBLICATIONS
Refereed Publications
93. Frischmann, P.D.; Sahli, B.J.; Guieu, S.; Patrick, B.O.; MacLachlan, M.J. “Sterically-Limited Self-Assembly of Pt4 Macrocycles into Discrete Non-covalent Nanotubes: Porous Supramolecular Tetramers and Hexamers” Chem. Eur. J. 2012, in press.
92. Hui, J.K.-H.; Jiang, J.; MacLachlan, M.J. “Unexpected Lyotropic Liquid Crystals from Ion-Induced Columnar Assembly of Schiff-Base Macrocycles” Can. J. Chem. 2012, in press. Invited article for “Geoffrey Ozin Special Issue”.
91. Freixa, Z.; Ponsico, S.; Frischmann, P.D.; MacLachlan, M.J.; Martínez-Belmonte, M.; Escudero-Adán, E.C.; van Leeuwen, P.W.N.M. “Bidentate ligands templated by a convex trimetallic bis(salphen) platform” Supramol. Catal. 2012, in press. Article.
90. Saiz-Poseu, J.; Martínez-Otero, A.; Roussel, T.; Hui, J.K.-H.; Montero, M.L.; Urcuyo, R.; MacLachlan, M.J.; Faraudo, J.; Ruiz-Molina, D. “Self-assembly of a catechol-based macrocycle at the liquid-solid interface: experiments and molecular dynamics simulations” Phys. Chem. Chem. Phys. 2012, in press. Article.
89. Shopsowitz, K.E.; Stahl, A.; Hamad, W.Y.; MacLachlan, M.J. “Hard Templating of Nanocrystalline Titanium Dioxide with Chiral Nematic Ordering” Angew. Chem. Int. Ed. 2012, 51, 6886-6890. Communication.
88. Shopsowitz, K.E.; Hamad, W.Y.; MacLachlan, M.J. “Flexible and Iridescent Chiral Nematic Mesoporous Organosilica Films” J. Am. Chem. Soc. 2012, 134, 867-870. Communication.
87. Frischmann, P.D.; Mehr, H.S.M.; Patrick, B.O.; Lelj, F.; MacLachlan, M.J. “The Role of Entropy and Autosolvation in Dimerization and Complexation of C60 by Zn7 Metallocavitands” Inorg. Chem. 2012, 51, 3443-3453.
86. Crane, A.K.; MacLachlan, M.J. “Portraits of Porosity: Porous Structures Based on Metal Salen Complexes” Eur. J. Inorg. Chem. 2012, 17-30. Invited Microreview.
85. Shopsowitz, K.E.; Hamad, W.Y.; MacLachlan, M.J. “Chiral Nematic Mesoporous Carbon Derived from Nanocrystalline Cellulose” Angew. Chem. Int. Ed. 2011, 50, 10991-10995.
• Identified as VIP by ACIE – all reviewers noted that this was a “very important paper” (top 5%)
• Highlight: Angew. Chem. Int. Ed. 2012, 51, 2008-2010.
84. Roy, X.; Chong, J.H.; Patrick, B.O.; MacLachlan, M.J. “Molecular scaffolding of Prussian blue analogues using a phenanthroline-extended triptycene ligand” Cryst. Growth Des. 2011, 11, 4551-4558. Article.
83. Roy, X.; Hui, J.K.-H.; Rabnawaz, M.; Liu, G.; MacLachlan, M.J. “Prussian Blue Nanocontainers: Selectively Permeable Hollow Metal-Organic Capsules from Block Ionomer Emulsion-Induced Assembly” J. Am. Chem. Soc. 2011, 133, 8420-8423. Communication.
82. Qi, H.; Shopsowitz, K.E.; Hamad, W.Y.; MacLachlan, M.J. “Chiral Nematic Assemblies of Silver Nanoparticles in Mesoporous Silica Thin Films” J. Am. Chem. Soc. 2011, 133, 3728-3731. Communication.
81. Vickers, S.M.; Frischmann, P.D.; MacLachlan, M.J. “A Family of Cadmium Acetate Coordination Networks with Structurally Diverse [Cd4(OAc)9(μ3-OH)]2- Secondary Building Units” Inorg. Chem. 2011, 50, 2957-2965. Article.
80. Shopsowitz, K.E.; Lelj, F.; MacLachlan, M.J. “Regioselectivity in the Nitration of Dialkoxybenzenes” J. Org. Chem. 2011, 76, 1285-1294. Article.
79. Roy, X.; Hui, J.K.-H.; Rabnawaz, M.; Liu, G.; MacLachlan, M.J. “Soluble Prussian Blue Nanoworms from the Assembly of Metal-Organic Block Ionomers” Angew. Chem. Int. Ed. 2011, 50, 1597-1602. Communication.
78. Guieu, S.; Crane, A.K.; MacLachlan, M.J. “Campestarenes: Novel Shape-Persistent Schiff Base Macrocycles with 5-Fold Symmetry” Chem. Commun. 2011, 47, 1169-1171. Communication.
77. Shopsowitz, K.E.; Qi, H.; Hamad, W.Y.; MacLachlan, M.J. “Free-Standing Mesoporous Silica with Tunable Chiral Nematic Structures” Nature 2010, 468, 422-425. Letter to Nature.
Highlights: The Vancouver Sun Newspaper, November 26, 2010, page A1/D3.
The Ottawa Citizen, The Montreal Gazette, Regina Leader Post, CBC.ca, November 26/27, 2010
Chemistry World – the magazine of the Royal Society of Chemistry
Physics World.com, November 20, 2010
CBC’s Quirks and Quarks – National Radio
ACCN – the magazine of the Canadian Society for Chemistry
Découverte (Radio-Canada) – National French CBC Television
76. Qi, H.; Roy, X.; Shopsowitz, K.E.; Hui, J.K.-H.; MacLachlan, M.J. “Liquid Crystal Templating in Ammonia: A Novel and Facile Route to Micro- and Mesoporous Metal Nitride/Carbon Composites” Angew. Chem. Int. Ed. 2010, 49, 9740-9743. Communication.
· Designated “Hot Paper” by editors of ACIE
75. Hui, J. K.-H.; MacLachlan, M.J. “Fibrous Aggregates From Dinuclear Zinc(II) Salphen Complexes” Dalton Trans. 2010, 39, 7310-7319. Article.
74. Frischmann, P.D.; Guieu, S.; Tabeshi, R.; MacLachlan, M.J. “Columnar Organization of Head-to-Tail Self-Assembled Pt4 Rings” J. Am. Chem. Soc. 2010, 132, 7668-7675. Article.
Highlight: Science July 2, 2010 (Editor’s Choice).
73. Jiang, J.; Leung, A.C.W.; MacLachlan, M.J. “Synthesis and Characterization of an Oligomeric Conjugated Metal-Containing Poly(p-phenylenevinylene) Analogue” Dalton Trans. 2010, 39, 6503-6508. Article.
72. Frischmann, P.D.; Facey, G.A.; Ghi, P.Y.; Gallant, A.J.; Bryce, D.L.; Lelj, F.; MacLachlan, M.J. “Capsule Formation, Carboxylate Exchange, and DFT Exploration of Cadmium Cluster Metallocavitands: Highly Dynamic Supramolecules” J. Am. Chem. Soc. 2010, 132, 3893-3908. Article.
71. Jiang, J.; MacLachlan, M.J. “Unsymmetrical Triangular Schiff Base Macrocycles With Cone Conformations” Org. Lett. 2010, 12, 1020-1023. Communication.
70. Hui, J.K.-H.; MacLachlan, M.J. “Metal-Containing Nanofibres via Coordination Chemistry” Coord. Chem. Rev. 2010, 254, 2363-2390. Invited review article for special issue on molecular electronics.
69. Hui, J.K.-H.; Frischmann, P.D.; Tso, C.-H.; Michal, C.A.; MacLachlan, M.J. “Spontaneous Hierarchical Assembly of Crown Ether-Like Macrocycles into Nanofibers and Microfibers Induced by Alkali Metal and Ammonium Salts” Chem. Eur. J. 2010, 16, 2453-2460. Article.
68. Hui, J.K.-H.; Yu, Z.; Mirfakhrai, T.; MacLachlan, M.J. “Supramolecular Assembly of Carbohydrate-Functionalized Salphen Metal Complexes” Chem. Eur. J. 2009, 15, 13456-13465. Article. One of 12 most accessed CEJ papers in 11/09.
67. Chong, J.H.; Jooya Ardakani, S.; Smith, K.J.; MacLachlan, M.J. “Triptycene-Based Metal Salphens - Exploiting Intrinsic Molecular Porosity for Gas Storage” Chem. Eur. J. 2009, 15, 11824-11828. Communication.
Highlight: Synfacts 2010, 2, 176.
66. Jiang, J.; MacLachlan, M.J. “Cationic Guest Inclusion in Widemouthed Schiff Base Macrocycles” Chem. Commun. 2009, 5695-5697. Communication.
65. Shopsowitz, K.E.; Edwards, D.; Gallant, A.J.; MacLachlan, M.J. “Highly Substituted Schiff Base Macrocycles via Hexasubstituted Benzene: A Convenient Double Duff Formylation of Catechol Derivatives” Tetrahedron 2009, 65, 8113-8119. Article.
64. Chong, J.H.; MacLachlan, M.J. “Iptycenes in Supramolecular and Materials Chemistry” Chem. Soc. Rev. 2009, 38, 3301-3315. Invited tutorial review.
63. Pietrangelo, A.; Patrick, B.O.; MacLachlan, M.J.; Wolf, M.O. “Conjugated Thiophene-Containing Oligoacenes Through Photocyclization: Bent Acenedithiophenes and a Thiahelicene” J. Org. Chem. 2009, 74, 4918-4926. Article.
62. Roy, X.; MacLachlan, M.J. “Coordination Chemistry: New Routes to Mesostructured Materials” Chem. Eur. J. 2009, 15, 6552-6559. Invited Concept article. One of 12 most accessed CEJ papers in 06/09.
61. Leung, A.C.W.; Hui, J.K.-H.; Chong, J.H.; MacLachlan, M.J. “Bimetallic Schiff Base Complexes: Models for Conjugated Shape-Persistent Metallopolymers” Dalton Trans. 2009, 5199-5210. Article.
59. Boden, B.N.; Hui, J.K.-H.; MacLachlan, M.J. “Social and Antisocial [3+3] Schiff Base Macrocycles with Isomeric Backbones” J. Org. Chem. 2008, 73, 8069-8072. Note.
58. Frischmann, P.D.; MacLachlan, M.J. “Schiff Base Macrocycles: Reliable Templates for Metallocavitands” Comments Inorg. Chem. 2008, 29, 26-45. Invited article.
57. Frischmann, P.D.; Jiang, J.; Hui, J.K.-H.; Grzybowski, J.J.; MacLachlan, M.J. “The Reversible-Irreversible Approach to Schiff Base Macrocycles: Access to Isomeric Macrocycles With Multiple Salphen Pockets” Org. Lett. 2008, 10, 1255-1258. Communication.
56. Pietrangelo, A.; Sih, B.C.; Boden, B.N.; Wang, Z.; Li, Q.; Chou, K.C.; MacLachlan, M.J.; Wolf, M.O. “Nonlinear Optical Properties of Schiff Base-Containing Conductive Polymer Films Electrodeposited in Microgravity” Adv. Mater. 2008, 20, 2280-2284. Communication.
55. Frischmann, P.D.; Gallant, A.J.; Chong, J.H.; MacLachlan, M.J. “Zinc Carboxylate Cluster Formation in Conjugated Metallomacrocycles: Evidence for Templation” Inorg. Chem. 2008, 47, 101-112. Article.
54. Roy, X.; Thompson, L.K.; Coombs, N.; MacLachlan, M.J. “Mesostructured Prussian Blue Analogues” Angew. Chem. Int. Ed. 2008, 47, 511-514. Communication and front cover of journal.
53. Boden, B.N.; Abdolmaleki, A.; Ma, C.T.-Z.; MacLachlan, M.J. “New Diformyldihydroxyaromatic Precursors for Luminescent Schiff Base Macrocycles: Synthesis, Characterization, and Condensation Studies” Can. J. Chem. 2008, 86, 50-64. Article.
52. Frischmann, P.D.; MacLachlan, M.J. “Capsule Formation in Novel Cadmium Cluster Metallocavitands” Chem. Commun. 2007, 4480 – 4482. Communication.
51. Chong, J.H.; MacLachlan, M.J. “Synthesis and Structural Investigation of New Triptycene-Based Ligands: En Route to Shape Persistent Dendrimers and Macrocycles With Large Free Volume” J. Org. Chem. 2007, 72, 8683-8690. Article.
50. Hui, J.K.H.; Yu, Z.; MacLachlan, M.J. “Supramolecular Assembly of Zinc Salphen Complexes: Access to Metal-Containing Gels and Nanofibers” Angew. Chem. Int. Ed. 2007, 46, 7980-7983. Communication.
49. Pietrangelo, A.; MacLachlan, M.J.; Wolf, M.O.; Patrick, B.O. “Synthesis and Structures of Novel Bent Acenedithiophenes” Org. Lett. 2007, 9, 3571-3573. Communication.
48. Leung, A.C.W.; MacLachlan, M.J. “ Poly (Salphenyleneethynylene)s: Soluble, Conjugated Metallopolymers That Exhibit Unique Supramolecular Crosslinking Behavior” J. Mater. Chem. 2007, 17, 1923-1932. Invited Article for Emerging Investigators Special Issue.
47. Leung A.C.W.; MacLachlan, M.J. “Schiff Base Complexes in Macromolecules” J. Inorg. Organomet. Poly. Mater., 2007,17, 57-89. Invited review.
46. Gallant, A.J.; Chong, J.H.; MacLachlan, M.J. “Heptametallic Bowl-Shaped Complexes Derived From Conjugated Schiff-base Macrocycles: Synthesis, Characterization, and X-ray Crystal Structures” Inorg. Chem. 2006, 45, 5248-5250. Communication.
45. Hui, J.K.-H.; MacLachlan, M.J. “[6+6] Schiff-base Macrocycles With 12 Imines: Giant Analogues of Cyclohexane” Chem. Commun. 2006, 2480-2482. Communication.
44. Boden, B.N.; Jardine, K.J.; Leung, A.C.W.; MacLachlan, M.J. “Tetraalkoxyphenanthrene: A New Precursor for Luminescent Conjugated Polymers” Org. Lett. 2006, 8, 1855-1858. Communication.
43. Chong, J.H.; MacLachlan, M.J. “Robust Non-Interpenetrating Coordination Frameworks From New Shape-Persistent Building-Blocks” Inorg. Chem. 2006, 45, 1442-1444. Communication.
42. MacLachlan, M.J. “Conjugated Shape-Persistent Macrocycles Via Schiff-Base Condensation: New Motifs for Supramolecular Chemistry” Pure Appl. Chem. 2006, 78, 873-888. Invited paper.
41. Sauer, M.; Yeung, C.; Chong, J.H.; Patrick, B.O.; MacLachlan, M.J. “N-Salicylideneanilines: Tautomers for Formation of Hydrogen-Bonded Capsules, Clefts and Chains” J. Org. Chem. 2006, 71, 775-783. Article.
40. Gallant, A.J.; Yun, M.; Sauer, M.; Yeung, C.S.; MacLachlan, M.J. “Tautomerization in Naphthalenediimines: A Keto-Enamine Schiff-base Macrocycle” Org. Lett. 2005, 7, 4827-4830. Communication.
39. Gallant, A.J.; Hui, J.K.-H.; Zahariev, F.E.; Wang, Y.A.; MacLachlan, M.J. “Synthesis, Structure, and Computational Studies of Soluble Conjugated Multidentate Macrocycles” J. Org. Chem. 2005, 70, 7936-7946. Article.
38. Ma, C.T.L.; MacLachlan, M.J. “Supramolecular Assembly and Coordination-Assisted Deaggregation of Multimetallic Macrocycles” Angew. Chem. Int. Ed. 2005, 44, 4178-4182. Communication.
37. Gallant, A.J.; Patrick, B.O.; MacLachlan, M.J. “Mild and Selective Reduction of Imines: Formation of an Unsymmetrical Macrocycle” J. Org. Chem. 2004, 69, 8739-8744. Article.
36. Ma, C.; Lo, A.; Abdolmaleki, A.; MacLachlan, M.J. “Synthesis and Metalation of Novel Fluorescent Conjugated Macrocycles” Org. Lett. 2004, 6, 3841-3844. Communication.
Highlight: Angew. Chem. Int. Ed. 2005, 44, 3806-3808.
35. Chong, J.H.; Sauer, M.; Patrick, B.O.; MacLachlan, M.J. “Highly Stable Keto-Enamine Salicylideneanilines” Org. Lett. 2003, 5, 3823-3826. Communication.
34. Gallant, A.J.; MacLachlan, M.J. “Ion-Induced Tubular Assembly of Conjugated Schiff-Base Macrocycles” Angew. Chem. Int. Ed. 2003, 42, 5307-5310. Communication. (Cited 87 times as of June 20, 2011)
· Designated “Hot Paper” by editors of ACIE
33. Leung, A.C.W.; Chong, J.H.; Patrick, B.O.; MacLachlan, M.J. “Poly(salphenyleneethynylenes): A New Class of Soluble, Conjugated, Metal-Containing Polymers” Macromolecules 2003, 36, 5051-5054. Communication.
Papers 1 – 32 are from my post-doctorate, PhD, and undergraduate research.
32. Bourke, S.C.; MacLachlan, M.J.; Lough, A.J.; Manners, I. “Ring-Opening Protonolysis of [1]Silaferrocenophanes as a Route to Stabilized Silylium Ions” Chem. Eur. J. 2005, 11, 1989-2000. Article.
31. Kwan, P.K.; MacLachlan, M.J.; Swager, T.M. “Highly Emissive Rotaxanated Conjugated Polymers” J. Am. Chem. Soc. 2004, 126, 8638-8639. Communication.
30. Asefa, T.; Kruk, M.; Coombs, N.; Grondey, H.; MacLachlan, M.J.; Jaroniec, M.; Ozin, G.A. “A Novel Route to Periodic Mesoporous Aminosilicas, PMAs: Ammonolysis of Periodic Mesoporous Organosilicas” J. Am. Chem. Soc. 2003, 125, 11662-11673. Article.
29. Thieme, K.; Bourke, S.C.; Zheng, J.; MacLachlan, M.J.; Zamanian, F.; Lough, A.J.; Manners, I. “Synthesis, Characterization, and Structures of Zircona- and Boracyclosiloxanes With Ferrocenyl Substituents” Can. J. Chem. 2003, 81, 1469-1480. Article.
28. Ginzburg, M.; MacLachlan, M.J.; Yang, S.M.; Coombs, N.; Coyle, T.W.; Raju, N.P.; Greedan, J.E.; Herber, R.H.; Ozin, G.A.; Manners, I. “Genesis of Nanostructured, Magnetically Tunable Ceramics From the Pyrolysis of Crosslinked Polyferrocenylsilane Networks: Formation of Shaped Macroscopic Objects and Micron Scale Patterns by Micromolding Inside Silicon Wafers” J. Am. Chem. Soc. 2002, 124, 2625-2639. Article.
27. Asefa, T.; Kruk, M.; MacLachlan, M.J.; Coombs, N.; Grondey, H.; Jaroniec, M.; Ozin, G.A. “Sequential Hydroboration-Alcoholysis and Epoxidation-Ring Opening Reactions of Vinyl Groups in Mesoporous Vinylsilica” Adv. Funct. Mater. 2001, 11, 447-456. Article.
26. MacLachlan, M.J.; Rose, A.; Swager, T.M. “A Rotaxane Exciplex” J. Am. Chem. Soc. 2001, 123, 9180-9181. Communication.
25. Asefa, T.; Kruk, M.; MacLachlan, M.J.; Coombs, N.; Grondey, H.; Jaroniec, M.; Ozin, G.A. "Novel Bifunctional Periodic Mesoporous Organosilicas, BPMOs: Synthesis, Characterizatrion, Properties and in-situ Selective Hydroboration - Alcoholysis Reactions of Functional Groups" J. Am. Chem. Soc. 2001, 123, 8520-8530. Article. (Cited 195 times as of Sept. 25, 2011)
24. Kulbaba, K.; MacLachlan, M.J.; Evans, C.E.B.; Manners, I. "Organometallic Gels: Characterization and Electrochemical Studies of Swellable, Thermally Crosslinked Poly(ferrocenylsilane)s" Macromol. Chem. Phys. 2001, 202, 1768-1775. Article.
23. Dag, O.; Yoshina-Ishii, C.; Asefa, T.; MacLachlan, M.J.; Grondey, H.; Coombs, N.; Ozin, G.A. "Oriented Periodic Mesoporous Organosilica (PMO) Film with Organic Functionality Inside the Channel Walls" Adv. Func. Mater. 2001, 11, 213-217. Article.
22. Jäkle, F.; Vejzovic, E.; Power-Billard, K.N.; MacLachlan, M.J.; Lough, A.J.; Manners, I. “Synthesis and Structure of a Hypercoordinate Silicon-Bridged [1]Ferrocenophane” Organometallics 2000, 19, 2826-2828. Communication.
21. Asefa, T.; Yoshina-Ishii, C.; MacLachlan, M.J.; Ozin, G.A. “New Nanocomposites: Putting Organic Function ‘Inside’ the Channel Walls of Periodic Mesoporous Silica” J. Mater. Chem. 2000, 10, 1751-1755. Feature Article.
20. MacLachlan, M.J.; Manners, I.; Ozin, G.A. “New (Inter)Faces: Polymers and Inorganic Materials” Adv. Mater. 2000, 12, 675-681. Research News Article.
19. MacLachlan, M.J.; Asefa, T.; Ozin, G.A. “Writing on the Wall With a New Synthetic Quill” Chem. Eur. J. 2000, 6, 2507-2511 (+ front cover). Invited Concept Article.
18. Asefa, T.; MacLachlan, M.J.; Grondey, H.; Coombs, N.; Ozin, G.A. “Metamorphic Channels in Periodic Mesoporous Methylenesilica: Synthesis, Characterization and Bridging Methylene to Terminal Methyl Transformation” Angew. Chem. Int. Ed. Engl. 2000, 39, 1808-1811. Communication. (Cited 184 times as of Sept. 25, 2011)
17. MacLachlan, M.J.; Scott, R.W.J.; Ozin, G.A.; McIntosh, D.F. “Self-Assembly of Microporous Thiogermanate Frameworks” J. Chem. Ed., 2000, 77, 630-632. Article.
16. MacLachlan, M.J.; Ginzburg, M.; Coombs, N.; Raju, N.P.; Greedan, J.E.; Ozin, G.A.; Manners, I. “Superparamagnetic Ceramic Nanocomposites: Synthesis and Pyrolysis of Ring-Opened Poly(ferrocenylsilanes) Inside Periodic Mesoporous Silica” J. Am. Chem. Soc. 2000, 122, 3878-3891. Article.
15. MacLachlan, M.J.; Bourke, S.C.; Lough, A.J.; Manners, I. “Ring-Opening Protonolysis of Strained Silicon-Containing Rings: A New Approach to Ions with Silylium Character” J. Am. Chem. Soc. 2000, 122, 2126-2127. Communication.
14. MacLachlan, M.J.; Ginzburg, M.; Coombs, N.; Coyle, T.W., Raju, N.P.; Greedan, J.E.; Ozin, G.A.; Manners, I. “Shaped Ceramics with Tunable Magnetic Properties from Metal-Containing Polymers” Science 2000, 287, 1460-1463. Communication. (Cited 171 times as of Sept. 25, 2011)
Highlights: Chemical and Engineering News, 78(9), 2000, p. 33.
MorgenWelt (Hamburg), February 28, 2000.
13. MacLachlan, M.J.; Zheng, J.; Thieme, K.; Lough, A.J.; Manners, I.; Mordas, C.; LeSuer, R.; Geiger, W.E.; Liable-Sands, L.M.; Rheingold, A.L. “Synthesis, Characterization, and Ring-Opening Polymerization of a Novel [1]Silaferrocenophane With Two Ferrocenyl Substituents at Silicon” Polyhedron, 2000, 19, 275-289. Article.
12. Asefa, T.; MacLachlan, M.J.; Coombs, N.; Ozin, G.A. “Periodic Mesoporous Organosilicas with Organic Groups Inside the Channel Walls” Nature 1999, 402, 867-871. Letter to Nature. (Cited 928 times as of Sept. 25, 2011)
Highlights: The National Post, December 28, 1999, page A17.
Chemical and Engineering News, 2000, 78(4), p.33 - 35. “Novel Mesoporous Hybrids Prepared”
11. Yoshina-Ishii, C.; Asefa, T.; Coombs, N.; MacLachlan, M.J.; Ozin, G.A. “Periodic mesoporous organosilicas, PMOs: fusion of organic and inorganic chemistry ‘inside’ the channel walls of hexagonal mesoporous silica” Chem. Commun. 1999, 2539-2540. Communication. (Cited 270 times as of Sept. 25, 2011)
10. MacLachlan, M.J.; Coombs, N.; Bedard, R.L.; White, S.; Thompson, L.K.; Ozin, G.A. “Mesostructured Metal Germanium Sulfides” J. Am. Chem. Soc. 1999, 121, 12005-12017. Article.
9. MacLachlan, M.J.; Zheng, J.; Lough, A.J.; Manners, I., Mordas, C.; LeSuer, R.; Geiger, W.E.; Liable-Sands, L.M.; Rheingold, A.L. “Ferrocenylsiloxane Chemistry: Synthesis and Characterization of Hexaferrocenyl-cyclotrisiloxane and Tetraferrocenyldisiloxanediol” Organometallics 1999, 18, 1337-1345. Article.
8. MacLachlan, M.J.; Coombs, N.; Ozin, G.A. “Non-Aqueous Supramolecular Assembly of Mesostructured Metal Germanium Sulfides From [Ge4S10]-4 Clusters” Nature 1999, 397, 681-684. Letter to Nature. (Cited 170 times as of Sept. 25, 2011)
Highlights: Chemical & Engineering News, “News of the Week” March 1, 1999, page 12.
Inside R&D Alert, February 26, 1999.
The Toronto Star, February 25, 1999, front page and page A2.
The Toronto Star, August 3, 1999, page A2.
The National Post, February 25, 1999, page A17.
The Bulletin, 1999, March 8, page 7.
The Varsity Newspaper, 1999, March 25, 1999, page 6.
The Ontario Business Report, April 1999, page 10.
The University of Toronto Magazine, June 1999, page 7.
7. MacLachlan, M.J.; Ginzburg, M.; Zheng, J.; Knöll, O.; Lough, A.J.; Manners, I. “Ring-Opening Addition of Hydrogen Chloride to Monocyclic and Spirocyclic [1]Ferrocenophanes: A Convenient and Controlled Route to Ferrocenylchlorosilanes and Germanes” New J. Chem. 1998, 22, 1409-1415. Article.
6. MacLachlan, M.J.; Petrov, Sr.; Bedard, R.L.; Manners, I.; Ozin, G.A. “Synthesis and Crystal Structure of d-GeS2, the First Germanium Sulfide with an Expanded Framework Structure” Angew. Chem. Int. Ed. Engl. 1998, 37, 2075-2079. Communication.
5. Nguyen, P.; Stojcevic, G.; Kulbaba, K.; MacLachlan, M.J.; Liu, X.-H.; Lough, A.J.; Manners, I. “Synthesis, Characterization, and Properties of Symmetrically Substituted, Ring-Opened Poly(ferrocenylalkoxy/ aryloxysilanes)” Macromolecules 1998, 31, 5977-5983. Article.
4. MacLachlan, M.J.; Lough, A.J.; Geiger, W.E.; Manners, I. “Synthesis, Structures, and Properties of Strained Spirocyclic [1]Sila- and [1]Germaferrocenophanes and Tetraferrocenylsilane” Organometallics 1998, 17, 1873-1883. Article.
3. MacLachlan, M.J.; Aroca, P.; Coombs, N.; Manners, I.; Ozin, G.A. “Ring-Opening Polymerization of a [1]Silaferrocenophane Within the Channels of Mesoporous Silica: Poly(ferrocenylsilane)-MCM-41 Precursors to Magnetic Iron Nanostructures” Adv. Mater. 1998, 10, 144-149. Communication.
2. MacLachlan, M.J.; Lough, A.J.; Manners, I. “Spirocyclic [1]Ferrocenophanes: Novel Crosslinking Agents for Ring-Opened Poly(ferrocenes)” Macromolecules 1996, 29, 8562-8564. Communication.
1. MacLachlan, M.J.; Park, M.K.; Thompson, L.K. “Coordination Compounds of Schiff-Base Ligands Derived from Diaminomaleonitrile (DMN): Mononuclear, Dinuclear, and Macrocyclic Derivatives” Inorg. Chem. 1996, 35, 5492-5499. Article.
Other Publications
(a) Book Chapters
M. J. MacLachlan, “Metal-Containing p-Conjugated Polymers” in “Frontiers in Transition Metal-Containing Polymers” (I. Manners & A. Abd-El-Aziz, eds.), John Wiley & Sons, 2007. pp. 161-215.
(b) Patents
MacLachlan, M.J.; Shopsowitz, K.E.; Hamad, W.Y.; Qi, H. “Inorganic Mesoporous Materials with Chiral Nematic Structures and Preparation Method Thereof” US Patent Application #13/076,469 filed March 31, 2011.
MacLachlan, M.J.; Shopsowitz, K.E.; Hamad, W.Y. “Chiral or Achiral Mesoporous Carbon” US Provisional Patent Application #61/484,756 filed May 11, 2011. PCT International Patent Application Filed May 10, 2012.
MacLachlan, M.J.; Shopsowitz, K.E.; Hamad, W.Y. “Mesoporous Silica and Organosilica Materials and Process for their Preparation” US Provisional Patent Application #61/485,207 filed May 12, 2011.
MacLachlan, M.J.; Shopsowitz, K.E.; Hamad, W.Y. “Chiral Nematic Nanocrystalline Oxides” US Provisional Patent Application. Filed August 2011. |
