简介: |
报告内容:Two-dimensional (2D) transition metal nitrides are in high demand
due to their promising physical and electrochemical properties. While
more than 20 2D transition metal carbides, such as Ti3C2Tx and other
carbide MXenes have been obtained, 2D metal nitrides are limited to only
a handful of synthesized materials so far. In terms of their superior
conductivity and stability, the field of 2D metal nitrides is of growing
significance. The bottleneck is a lack of known synthesis routes. For
example, there are few bulk layered transition metal ternary nitrides
known and so far only 2D Ti4N3 and Ti2N (nitride MXene) have been
successfully exfoliated from nitride MAX phases. Hence we recently
developed a salt-templating method, which has already produced 2D MoN,
V2N, W2N, W2N3 and Mn3N2. In this procedure, a metal-containing
precursor is mixed with a salt and then treated at high temperatures
under ammonia flow. A 2D metal nitride is obtained due to the lattice
match between the surface of the salt and the target product. X-ray
diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray pair
distribution function (PDF) analysis confirmed the various nitrides
structures. We will also discuss the potential applications of 2D metal
nitrides in energy storage and beyond. |