简介: |
In the major part of this lecture, I will present a model for drying
shrinkage of mesoporous materials which considers capillary and
surface adsorption effects. As such it can be applied over a wide
range of humidity, a concern for nuclear waste packages which has to
be disposed in environment of low humidity for at least 50 years in
France. The model is derived from thermodynamics and needs as input
only the sorption isotherm from which a BJH analysis provides with all
information. The model is validated on many different materials during
adsorption and desorption. In particular experimental strains measured
during the desorption of cement paste and vicor glass exhibit
non-monotonous variations which are captured with the model, without
any additional fitting parameters. Physical insights gained with the
model permit to understand the dominant forces at stake during the process of drying. In the last part of this lecture, I will present
briefly a model suited for microporous materials such as coal. This
model was applied to explain the transient permeability of fractured
coal seams as observed in the field.
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