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报告题目:
同步辐射光电离质谱技术在燃烧及其它研究中的应用
 报告人:
齐飞
中科大教授
报告时间:
2009-11-27 10:00
报告地点:
热能系馆报告厅
主办单位:
热能系
  简介:

齐飞教授简介:齐飞,博士,教授,博士生导师,男,1968年1月生。2009年国家杰出青年基金获得者。2002年中国科学院“引进海外杰出人才”获得者。1991年7月毕业于安徽师范大学物理系,1997年7月获中国科学技术大学博士学位,并留国家同步辐射实验室工作。1998年10月 - 2001年9月在美国Lawrence Berkeley National Laboratory的the Advanced Light Source (ALS) 作博士后;2001年9月 – 2003年2月在美国Sandia National Laboratories的Combustion Research Facility (CRF)作博士后;2003年2月回中国科技大学国家同步辐射实验室工作。多年来致力于同步辐射的应用研究,包括自由基、分子、团簇的光电离和光解离研究,金属有机化合物的光电离等。与国外同行合作,首次将同步辐射应用到燃烧与火焰的研究,在ALS建立了第一个燃烧实
验站。目前主要利用同步辐射和分子束质谱研究燃烧与大气污染。近年来,在J. Am
Chem. Soc., J. Chem. Phys., J. Phys. Chem. A, Chem. Phys. Lett.等国内外杂志发表60余篇。

主要研究方向:

利用同步辐射和分子束质谱技术进行下列研究:
1. 低压层流预混火焰
2. 高温空气燃烧技术
3. 卷烟烟气分析
4. 催化燃烧
5. 汽车发动机尾气分析
6. 利用多级电离室测量碳氢化合物的绝对电离能


发表的主要文章(1999年以后发表的部分文章):
1. Selective detection of isomers with photoionization mass spectrometry for
studies of hydrocarbon flame chemistry
J. Chem. Phys. 119 (16): 8356-8365, 2003

2. Identifying combustion intermediates via tunable vacuum ultraviolet
photoionization mass spectrometry
Combustion Science and Technology (accepted)

3. REMPI Temperature measurement in molecular beams sampled from
low-pressure flames
Proc. Combust. Inst. 29, 2627-2633, 2003

4. Photodissociation of propylene sulfide at 193 nm: A photofragment
translational spectroscopy study with VUV synchrotron radiation
J. Phys. Chem. A 106 (46): 11017-11024, 2002

5. A Gaussian-3 study of the photodissociation channels of propylene sulfide
J. Phys. Chem. A 106 (46): 11025-11028, 2002

6. Dissociation channels of the 1-propenyl radical and its photolytic
precursor cis-1-bromopropenet
J. Phys. Chem. A 106 (45): 10831-10842, 2002

7. Dissociation channels of the 1-propenyl radical and its photolytic
precursor cis-1-bromopropene
J. Phys. Chem. A 106 (45): 10965-10967, 2002
 
8. Exclusive production of excited-state sulfur (D1) atoms from 193 nm
photolysis of thietane
Chem. Phys. Lett. 357 (3-4): 204-208, 2002

9. C-Cl bond fission, HCl elimination, and secondary radical decomposition
in the 193 nm photodissociation of allyl chloride
J. Chem. Phys. 116 (7): 2763-2775, 2002

10. Photofragment translational spectroscopy of 1,2-butadiene at 193 nm
J. Chem. Phys. 115 (18): 8359-8365, 2001

11. The photodissociation dynamics of cyclic sulfides probed with tunable
undulator radiation
Journal of Electron Spectroscopy and Related Phenomena 119 (2-3): 127-145,
2001

12. Experimental and theoretical studies of the VUV photoionization of
chloropropylene oxide
J. Phys. Chem. A 105 (13): 2973-2979, 2001

13. Competing isomeric product channels in the 193 nm photodissociation of
2-chloropropene and in the unimolecular dissociation of the 2-propenyl
radical
 J. Chem. Phys. 114 (10): 4505-4521, 2001

14. The ultraviolet photochemistry of phenylacetylene and the enthalpy of
formation of 1,3,5-hexatriyne
J. Am. Chem. Soc. 123 (4): 671-676, 2001
 
15. Photodissociation of ethylene sulfide at 193 nm: A photofragment
translational spectroscopy study with VUV synchrotron radiation and ab
initio calculations
J. Am. Chem. Soc. 123 (1): 148-161, 2001
 
16. Internal energy dependence of the H+allene H+propyne product branching
from the unimolecular dissociation of 2-propenyl radicals
J. Phys. Chem. A 104 (48): 11261-11264, 2000

17. Characterization of nitrogen-containing radical products from the
photodissociation of trimethylamine using photoionization detection
J. Chem. Phys. 113 (8): 3088-3097, 2000

18. Evidence of triplet ethylene produced from photodissociation of ethylene
sulfide
J. Chem. Phys. 112 (24): 10707-10710, 2000

19. 193 nm photodissociation of thiophene probed using synchrotron radiation
J. Phys. Chem. A 103 (42): 8351-8358, 1999

20. A vacuum ultraviolet photoionization mass spectrometric study of
propylene oxide in the photon energy region of 10-40 eV
J. Phys. Chem. A 103 (41): 8179-8186, 1999

21. Ultraviolet photodissociation of furan probed by tunable synchrotron
radiation
J. Chem. Phys. 111 (1): 100-107, 1999

22. A vacuum ultraviolet photoionization mass spectrometric study of
ethylene oxide in the photon energy region of 10-40 eV

J. Phys. Chem. A 103 (21): 4155-4161, 1999

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