出生年月: 1971年5月       国籍: 中国          

 

 

2001 – 2005         美国耶鲁大学博士 (金属有机化学方向), 并获得耶鲁大学2005年最佳化学博士论文奖. 导师: Robert H. Crabtree 教授。网址http://www.chem.yale.edu/~crabtree

1999 – 2001         美国纽约州立大学Albany 分校化学系研究生课程学习，后转学。

1996 -  1997       中科院上海有机化学研究所

1991 – 1996         复旦大学化学系，学士学位 (其中含一年军训)

 

 

2010-今                中国科学院大连化学物理研究所研究员，入选中科院百人计划

2008 – 2009         美国Scripps 研究所(Florida 分院)，催化助理教授(Assistant Prof. of Catalysis）

2006 – 2008         新加坡南洋理工大学化学及生物化学系助理教授（tenure-track）

2005 – 2006         美国加州理工学院化学系博士后. 导师: John Bercaw 教授

1997 – 1999         上海市轻工业研究所, 化学师anghai   

 

 

2005年                耶鲁大学研究生院Richard Wolfgang最佳(化学)博士论文奖

2002年                英国Johnson Matthey 公司Rhodium Bicentennial 奖学金

2000年                美国纽约州立大学Albany 分校Benjamin Smith奖学金.

 

(1)   能源及催化

·             金属均相催化剂作用下的甲烷的碳-氢键的活化及高选择性的甲烷-甲醇转化

·             金属甲基配合物的现场合成及官能化

·             金属均相催化剂作用下的甲烷的燃料电池的基础研究

·             锌催化下的航空燃料（triptane）的催化合成

 (2)       金属有机合成化学

·               结构新颖的氮杂环卡宾的稀土后过渡金属化合物 (铱, 铑, 钯, 铂, 镍, 钌 等)

·               非经典含氮杂环卡宾化合物的结构,合成及催化应用

·               手性氮杂环卡宾化合物的合成

·               非眯唑类氮杂环卡宾化合物的合成

·               具有灵活的配位方式的多齿螯合配体的后过渡金属化合物：合成、结构和机理

·               含有Cp*(C₅Me₅) 配体的金属化合物的合成

(3)   金属有机化学反应机理

·               分子内及分子间的 C-H 和 C-C 键 的活化

·               化学计量的及催化的(手性)氢转移反应

·               炔烃和过渡金属的化学计量及催化反应

·               金属-氢键的插入反应

·               金属有机化学基元反应

(4)                均相催化反应及有机合成方法学

·                有机分子的C-H 和 C-C 键的催化活化及官能化

·                烯和炔的氢胺化反应

·               含炔烃的C-C键的形成反应

·               钯和铑催化的氧化反应

 

2006 – 2008          新加坡南洋理工大学（英语教学）

《普通化学》 (平均210人/年)，《化学波谱方法学》 (平均60人/年), 本科生和研究生《金属有机化学》 (平均30人/年)，指导8名本科生的暑假研究工作。

2002 – 2005      耶鲁大学本科部 (Yale College) 化学和物理答疑辅导教师，总计辅导>800人次。

2001 – 2002     耶鲁大学化学系教学助理（Teaching Assistant）

 

 

-南洋理工大学任助理教授期间，指导五名博士生和硕士生，其中已毕业博士生两名 (宋国勇，2008，彭红梅2009), 已毕业硕士生一名 (王心娇，2007)。其余学生因本人离职而转组。

-美国Scripps 研究所(Florida 分院)任助理教授期间，指导博士后一名。

-在大连化物所指导联合培养生研究生6名，博士后1名，博士职工2名。

 

 

1. “A Rare h²-Butadienyl Complex from an Alkyne Double Insertion with Double Vinylidene Rearrangement,” Li, X.; Incarvito, C. D.; Crabtree, R. H. J. Am. Chem. Soc., 2003, 125, 3698-3699.

2. “Stoichiometric C-C Coupling Reactions in the Coordination Sphere of an Iridium(III) Alkyl,” Li, X.; Appelhans, L. N.; Faller, J. W.; Crabtree, R. H. Organometallics 2004, 23, 3378-3387.

3. “Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics,” Chianese, A. R.; Li, X.; Janzen, M. C.; Faller, J. W.; Crabtree, R. H.  Organometallics 2003, 22, 1663-1667.

4. “Electronic and Steric Effects in the Insertion of Alkyns into Iridium Hydrides,” Li, X.; Vogel, T.; Incarvito, C. D.; Crabtree, R. H. Organometallics 2005, 24, 62-76.

5. “Intramolecular Oxygen Transfer from Nitro Groups to CºC bonds Mediated by Iridium Hydrides,” Li, X.; Incarvito, C. D.; Vogel, T.; Crabtree, R. H. Organometallics 2005, 24, 3066-3073.

6. “Cycloiridation of Unsaturated Ketones, Esters and Acetophenones” Li, X.; Chen, P.; Faller, J. W.; and Crabtree R. H. Organometallics 2005, 24, 4810-4815.

7. “Intramolecular Alkyne Hydroalkoxylation and Hydroamination Catalyzed by Iridium Hydrides,” Li, X.; Chianese, A. R.; Vogel, T.; Crabtree, R. H. Org. Lett. 2005, 7, 5437-5440.

8. “On the Mechanism of the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide” Bercaw, J. E.; Diaconescu, P. L.; Grubbs, R. H.; Kay, R. D.; Labinger, J. A., Li, X., Mehrkhodavandi, P. M.; Morris, G. E.; Sunley, G. J.; Vagner, P. (作者依字母排序) J. Org. Chem. 2006, 71, 8907.

9. “Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid”, Bercaw, J. E.; Grubbs, R. H.; Hazari, N.; Labinger, J. A.;  Li, X. (作者依字母排序) Chem. Commun. 2007, 2974.

10. “Ir(III)-induced C-bound to N-bound Tautomerization of an N-Heterocyclic Carbene”, Wang, X.^s, Chen, H.; Li, X.^* Organometallics 2007, 26, 4684. (^s denotes student in Xingwei Li’s research group)

11. “Iridium Hydrides with Abnormal N-Heterocyclic Carbenes via Highly Selective C-H Activation”, Song, G.^s, Wang, X.^s, Li. Y. and Li. X.^* Organometallics, 2008, 27, 1187.

12. “Rh and Ir Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine”, Song, G.^s; Zhang, Y^s. and Li, X.^* Organometallics 2008, 27, 1936.

13. “Hydrogen Bonding-Assisted Tautomerization of Pyridine Moieties in the Coordination Sphere of an Ir(I) Complex”, Song, G.^s, Li, Y.; Chen, S.^s and Li, X.^* Chem. Commun. 2008, 3558.

14. “Synthesis, Structures, and Solution Dynamics of Palladium Complexes of Quinoline-Functionalized N-Heterocyclic Carbenes”, Peng, H.^s; Song, G.^s; and Li. X.^* Inorg. Chem. 2008, 47, 8031.

15. “Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties” Peng, H.^s; Webster, R. D.^*; Li, X.^* Organometallics 2008, 27, 4484.

16.  “Pyridine-Based N-Heterocyclic Carbene Hydride Complexes of Iridium via C-H Activation” Song, G.^s; Zhang, Y.^s; Su, Y.^s; Deng, W.; Han, K. and Li, X.^* Organometallics 2008, 27, 6193-6201.

17. “Chelation-Assisted Rhodium Hydride-Catalyzed Regioselective H/D Exchange in Arenes” Chen, S.^s; Song, G.^s; Li, X.^* Tetrahedron Lett. 2008, 49, 6929.

18. “An efficient synthesis of chiral phosphinyl oxide pyrrolidines and their application to asymmetric direct aldol reactions” Liu, X.^*; Le, T. N.; Lu, Y.; Xiao, Y.; Ma, J.; Li, X. Org. Bimolecular Chem. 2008, 6, 3997.

19.  “A Rare h³-binding mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes” Panichakul, D.^s; Su, Y.^s; Li, Y.; Deng, W.-Q.; Zhao, J.^*; Li, X.^* Organometallics 2008, 6390-6392.

20.  “Chelation Assisted Carbon-Halogen Bond Activation by a Rhodium(I) Complex” Chen, S.^s; Li, Y.; Zhao, J.^*; Li, X.^*  Inorg. Chem. 2009, 48, 1198.

21.  “Iridium and Rhodium 2-Methyleneimidazoline Complexes from Selective sp³ C-H Activation of 2-Methylmidazoliums”, Song, G.^s; Li, X.^* Song, Z., Zhao, J.*, Zhang, H. Chem.- Eur. J. 2009, 15, 5535.

22.  “1,3-Dinitrone Pincer Complexes of Pd and Ni: Synthesis, Structural Characterization, and Catalysis”, Zhang, Y.^s; Song, G.^s; Zhao, J.;* Pan, C.-L.；Li, X.^*Organometallics 2009, 28, 3233. (a most accessed article in Organometallics from April to June 2009)

23. “Rh-Catalyzed Head-to-Tail Dimerization of 1-Alkynes and Subsequent Gold-Catalyzed Hydroamination Reactions” Peng, H.^s; Zhao, J.^*; Li, X.^*, Adv. Syn. Catal. 2009, 351, 1371.

24. “Stabilization of an Imidosamarium(III) Cubane by Amidinates” Pan, C. L.; Zhang, H.*; Li, X.*   Inorg. Chem. 2009, 48, 6344.

25. “Anion Exchange-Triggered 1,3-Shift of NH Proton to Iridium in Protic N-Heterocyclic Carbenes: Hydrogen Bonding and Ion-Pairing Effects.” G. Song,^p Y. Su, R. A. Periana, R. H. Crabtree, K. Han*, H. Zhang and X. Li* Angew. Chem. Int. Ed. 2010, 49, 912-917.

26. “Ruthenium ONO-type Pincer Complex: Synthesis, Structural Characterization, and Catalysis” Zhang, Y.^s; Li, X.^*; Hong, S. H.^* Adv. Syn. Catal. 2010, 352, 1779.

27. “Rh-Catalyzed Oxidative Coupling between Primary and Secondary Benzamides and Alkynes: Synthesis of Polycyclic Amides” Song, G.^s; Chen, D.; Pan, C.-L.; Crabtree, R. H.; Li, X.* J. Org. Chem. 2010, 75, 7487.

28. “Rh(III)-catalyzed Tandem Oxidative Olefination-Michael Reactions between Aryl Carboxamides and Alkenes” Wang, F.; Song, G.; Li, X.* Org. Lett. 2010, 12, 5430-5433.

29.  “Synthesis of 2-Pyridones and Iminoesters via Rh(III)-Catalyzed Oxidative Coupling between Acrylamides and Alkynes” Su, Y.; Zhao, M.; Han, K.; Song, G.; Li, X.* Org. Lett. 2010, 12, 5462-5465.

30. "Rh(III)-Catalyzed Oxidative Coupling of N-Aryl-2-aminopyridine with Alkynes and Alkenes" Chen, J.; Song, G.; Pan, C.-L.; Li, X.* Org. Lett. 2010, 12, 5426-5429.

31. “Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes” by Zhang, X.; Chen, D.; Zhao, M.; Zhao, J.; Jia, A. Li, X.* Adv. Synth. Catal. 2011, 353, 719-723.

32. “Palladium-Catalyzed Oxidative Cross-Coupling between Pyridine N-Oxides and Indoles” Gong, X.; Song, G.; Zhang, H.; Li, X.* Org. Lett. 2011,13,1766-1769.

33. “Ir-Mediated Tautomerization of Substituted 2,3-Bipyridyls” Su, Y.^s; Song, G.^s; Han, K.*; Li, X.*, J. Organomet. Chem. 2011, 696, 1640-1646.

34. “Pd(0)-Catalyzed Diarylation of sp³ C-H Bonds in (2-Azaaryl)methanes” Song, G.; Su, Y.; Han, K.; Gong, X.; Li, X.^* Org. Lett. 2011, ASAP

35. “Synthesis of N-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling” Chen, J.; Sun,Y.; Li, X.* J. Org. Chem. 2011, ASAP

36. “Gold a-Oxo Carbenoids in Catalysis: Catalytic O-Atom Transfer to Alkynes” Xiao, J.; Li, X.* (review article) accepted by Angew Chem. Int. Ed. 2011

37. “Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III)”, Wang, F.; Song, G.; Du, Z.; Li, X.* J. Org. Chem. 2011 ASAP.